Total Synthesis of the Proposed Structure of Indolyl 1,2-Propanediol Alkaloid, 1-(1H-Indol-3-yloxy)propan-2-ol by Momoko Kimata & Takumi Abe
Author:Momoko Kimata & Takumi Abe
Format: pdf
Tags: The first total synthesis of the proposed structure of unprecedented indolyl derivative bearing 1,2-propanediol moiety is described. Isomerization of 3-alkoxyindolines through indolenium intermediates was the key step in the total synthesis. 1H, 13C-NMR, IR, and HRMS spectra of the synthetic compound drastically differed to those of the originally reported structure, which suggests the natural product requires revision., 1-(1H-indol-3-yloxy)propan-2-ol; indole alkaloid; isomerization; silver; umpolung
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